UDK 536.46
ANALYSIS OF THE ENVIRONMENTAL SITUATION ON STORAGE SITE OF ROCKET FUEL
М. Е. Baranov1, L. А. Gerasimova1, V. E. Gerasimova1, S. V. Khizhnyak2
1Reshetnev Siberian State Aerospace University 31, Krasnoyarsky Rabochy Av., Krasnoyarsk, 660037, Russian Federation 2Krasnoyarsk State Agrarian University 90, Mira Av., Krasnoyarsk, 660049, Russian Federation
The object of the study was the soil and the soil in the storage area of KRT military unit 12313 (technical missile base), which was located in 11 km south-west of Pamyati 13 Bortsov village Emelyanovsky district of Krasnoyarsk region. The levels of radiation (exposure and equivalent doses of external gamma-radiation levels of alpha- and betafields, the specific activity of radionuclides, including man-made cesium-137) on the object correspond to background characteristics. The concentration of KRT in soil is 0.001 mg/l, which corresponds to the level of “Danger” according to the testimony of the army device of chemical investigation. Bioindication with the use of Pinus sylvestris L., as well as the bioassay using Lepidium sativum L. showed that after the elimination of the military unit near the settlement of Pamyati 13 Bortsov due to contact with soil significant amount of KRT was unfavorable ecological situation that has reflected in maintaining a high level of phytotoxicity of soil. Special structures, debris, remains of tanks, fuel valves with chemical contaminants are ownerless there. This requires conducting the reclamation of the area. When carrying out detoxification and rehabilitation of soils a strong spatial irregularity of the level of residual contamination must be considered. To calculate the volume and technology of works it is recommended to carry out microbiological analysis of soil and to make a detailed map of phytotoxicity. When drawing the map of phytotoxicity it is recommended to consider the following set of indicators: the energy of the germination test cultures, mitotic index, and length of seedlings on the 5th day of cultivation.
Keywords: unsymmetrical dimethylhydrazine, soil, phytotoxicity, bioassay, reclamation.
References

1. Zanozina V. F., Hmeleva M. V., Samsonova L. E., Zorin A. D., Goryacheva N. M., Markova M. L., Gareev D. R. [Independent environmental monitoring of the environment around center for the elimination of Intercontinental ballistic missiles] Ekologicheskie problemy promyishlennykh gorodov. Sbornik nauchnykh trudov po materialam 6-y Vserossiyskoy nauchnoprakticheskoy konferentsii s mezhdunarodnyim uchastiem. Ch. 1. Saratov, 2013, P. 192–194 (In Russ.).

2. Kuchkin A. G., Hizhnyak S. V., Muchkina E. Ya., Baranov M. E., Anpilogov V. N. [Analysis of the environmental situation at the sites of operation of rocket and space technology of the Ministry of defence of the Russian Federation]. Vestnik SibGAU. 2003, No. 2(42), P. 91–95 (In Russ.).

3. Bushmarin A. B., Laskin B. M., Pimkin V. G., Solov’ev V. V., Careva O. A. [Integrated environmental assessment of areas separating from parts of rockets at the site “Plesetsk”]. Materialy nauchn. prakt. konf. “Ehkologicheskie aspekty vozdeystviya komponentov zhidkikh raketnykh topliv na okruzhayushchuyu sredu”. St. Petersburg, Prikladnaya himiya Publ., 1996, P. 5–8 (In Russ.).

4. Kirk-Othmer. Entsiklopediya khimicheskoj tekhnologii [Encyclopedia of Chemical Technology]. Available at: http: //chemistrychemists.com/chemister/Polytom/polytom.htm (accessed 30.08.2016).

5. Bol’shakov G. F. Khimiya i tekhnologiya komponentov zhidkogo raketnogo topliva [Chemistry and technology of components of liquid rocket fuel]. Leningrad, Himiya Publ., 1983, 320 p.

6. Sedova G. I., Kovalenko I. V. [To the question about the stability of UDMH in podsollike sandy loam soil]. Byulleten’ toksikologii, gigieny i profpatologii raketnykh topliv. 1976, No. 23, P. 163 (In Russ.).

7. Kushneva V. S, Gorshkova R. B. Spravochnik po toksikologii i gigienicheskim normativam (PDK) potetscial’no opasnykh khimicheskikh veshchestv [Handbook of toxicology and hygienic standards (Mac) of potentially hazardous chemicals]. Moscow, IzdAt Publ., 1999, 272 p.

8. Sergejchik S. A. Rasteniya i ekologiya [Plants and ecology]. Minsk, Urozhay Publ., 1997, 224 p.

9. Zaharov V. M. Zdorov’e sredy [The health of the environment]. Moscow, CEHPR Publ., 2000, 65 p.

10. Fedorova A. I., Nikol’skaya A. N. Praktikum po ehkologii i okhrane okruzhayushchej sredy [Workshop on ecology and environmental protection]. Moscow, Vlados Publ., 2001, 288 p.

11. Ermakov E. I., Popova G. G., Petrova Z. M. [The influence of the asymmetrical dimethylhydrazine on the condition of the soil-plant system]. Ekologicheskie aspekty vozdeystviya komponentov zhidkikh raketnykh topliv na okruzhayushchuyu sredu. Mat. nauchnopraktich. konf. St. Petersburg, RNC Prikladnaya himiya Publ., 1996, P. 15–19 (In Russ.).

12. GOST 17.4.4.02–84. Okhrana prirody. Pochvy. Metody otbora i podgotovki prob dlya khimicheskogo, bakteriologicheskogo, gel’mintologicheskogo analiza [State Standard 17.4.4.02-84. Protection of Nature. Soils. Methods of sampling and sample preparation for chemical, bacteriological, helminthological analysis]. Moscow, Standartinform Publ., 1984, P. 6–8 (In Russ.).

13. Sedova G. I., Glebova L. F. [The methodology for the assessment of soil pollution by components of rocket fuels]. Byulleten’ toksikologii, gigieny i profpatologii raketnykh topliv. 1978, No. 31, P. 84 (In Russ.).

14. Allov I. A. Tsitofiziologiya i patologiya mitoza [Cytophysiology and pathology of mitosis]. Moscow, Medicina Publ., 1972, 264 p.

15. Pausheva Z. P. Praktikum po tsitologii rastenij [Workshop on plants cytology]. Moscow, Agropromizdat Publ., 1988, 271 p.

16. GOST 12038–84 Semena sel’skohozyajstvennykh kul’tur. Metody opredeleniya vskhozhesti [State Standard 12038-84. Seeds of agricultural crops. Methods for determination of germination]. Moscow, Standartinform Publ., 1984, P. 5–7 (In Russ.).

17. Kovylina O. P., Zarubina I. A., Kovylin A. N. [Assessment of the vitality of Scots pine in the area of technogenic pollution]. Khvoynye boreal’noy zony. 2008, No. 3, P. 284–289 (In Russ.).

18. Zrelov V. N., Seregin E. P. Zhidkie raketnye topliva [Liquid rocket fuel]. Moscow, Himiya Publ., 1975, 320 p.

19. Bagdasaryan A. S. Biotestirovanie pochv tekhnogennykh zon gorodskikh territorij s ispol’zovaniem rastitel’nykh organizmov. Diss. Kand. Biolog. nauk. [Biotesting of soils of technogenic zones of urban areas with vegetable organisms. Diss. candidate biolog. sci.]. Stavropol’, 2005, 159 p.


Baranov Mikhail Evgen’evich – Cand. Sc., docent, faculty of Military training, Reshetnev Siberian State

Aerospace University. E-mail: me_baranov@mail.ru.

Gerasimova Ludmila Anatol’evna – Cand. Sc., docent, docent of Department of Environmental engineering,

faculty of Mechanical engineering and mechatronics, Reshetnev Siberian State Aerospace University. E-mail:

Lyu-Gerasimova@yandex.ru.

Gerasimova Valeria Evgen’evna – senior teacher, Department of Finance and credit, Reshetnev Siberian State

Aerospace University. E-mail: I-ejik @yandex.ru.

Khizhnyak Sergei Vital’evich – Dr. Sc., docent, professor of Department of Ecology and natural sciences,

Krasnoyarsk State Agrarian University. E-mail: Khizhnyak @yandex.ru.